Study of Free Energy Transfer in 10, 20 and 30% Dioxane in Dioxane-Water System for Deprotonation of Glycine and Related Thermodynamic Quantities At 298.15 K by E.M.F Measurement

The deprotonation constant of glycine in 10%, 20% and 30% dioxane dioxane-water system at 298.15 K was determined using the cell: H2(Pt) | Glycine, HCl, X% Dioxane, Hg2Cl2 Hg …(C-1) m1 m2 e.mf. cell given by E = E0 - (2.303RT/F) (log mH+ mCl_ + log ?H+ ?Cl_) …(1) where ?Cl_ (2A’√μ/(1+√μ) ) ?1μ (Modified Davies Equation) …(2) which has been B Prasad our laboratory called modified equation for calculating activity coefficient hence can be calculated formula: (E0 E)/K (2A’ √μ/(1+ √μ)) …(3) Therefore Free energy transfer 10, 20 during determination K.